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Glyphosate 62% MSDS
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
| PRODUCT NAME: | Farmway Glyphosate 62% Manufacturing Concentrate |
| SYNONYMS: | None |
| EPA REGISTRATION NO.: | 86277-1 |
| MANUFACTURER: | Farmway, Inc. |
| ADDRESS: | 113 Barksdale Professional Center Newark, DE 19711 |
| EMAIL: | farmway@farmwayus.com |
| EMERGENCY PHONE: | 1(800) 222-1222 |
| CHEMTREC PHONE: | 1(800) 424-9300 |
| CHEMICAL NAME: | glyphosate isopropylammonium or glyphosate, N-(phosphonomethyl)-glycine, as isopropylamine salt |
| N-(phosphonomethyl)glycine - isopropylamine (1:1) or isopropylammonium N-(phosphonomethyl)glycinate | |
| CHEMICAL FAMILY: | glycine |
| CHEMICAL FORMULA: | C6H17N2O5P |
| PRODUCT USE: | For the manufacture of herbicides |
| PREPARED BY: | Farmway, Inc. |
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
ACTIVE INGREDIENT: glyphosate isopropylamine salt
| CAS NO. 38641-94-0 | % WT 62.0 | % VOL 62.0 | SARA 313 REPORTABLE No |
| ppm | mg/m3 | ||
| OSHA PEL-TWA: | N/A | N/A | |
| OSHA PEL STEL : | N/A | N/A | |
| OSHA PEL CEILING: | N/A | N/A | |
| ACGIH TLV-TWA: | N/A | N/A | |
| ACGIH TLV STEL: | N/A | N/A | |
| ACGIH TLV CEILING: | N/A | N/A |
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: CAUTION. Causes moderate eye irritation. Avoid contact with eyes or clothing. Avoid breathing vapors or mist.
ROUTES OF ENTRY: Eye and dermal contact.
POTENTIAL HEALTH EFFECTS
EYES: May cause temporary eye irritation.
SKIN: Not expected to produce significant adverse effects when recommended use instructions are followed.
INHALATION: Not expected to produce significant adverse effects when recommended use instructions are followed.
CARCINOGENICITY – None known.
SECTION 4: FIRST AID MEASURES
FIRST AID |
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If on skin or clothing |
Take off contaminated clothing. |
If swallowed: |
Call a poison control center or doctor immediately for treatment advice. |
If in eyes: |
Hold eye open and rinse slowly and gently with water for 15-20 minutes. |
HOT LINE NUMBER |
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Note to Physician – Probably mucosal damage may contraindicate the use of gastric lavage. |
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SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, UPPER: Not applicable.
(% BY VOLUME) LOWER: Not applicable.
FLASH POINT: Not available.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABILITY: Not applicable.
EXTINGUISHING MEDIA: Water, foam, dry chemical, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: Evacuate personnel to safe area. Keep personnel removed and upwind of fire. Wear full protective clothing and self-contained breathing apparatus. If water spray is used to fight fire, dike and collect runoff. Prevent the use of contaminated buildings, area, and equipment until decontaminated. Water runoff can cause environmental damage.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may produce irritating and possibly toxic gases including carbon monoxide, nitrogen oxides (NOx), phosphorus oxides.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.
SECTION 6 NOTES:
Small Spill: Absorb small spills with sand, vermiculite or other inert absorbent. Place contaminated material in appropriate container for disposal. Scrub area with hard water detergent. Pick up wash liquid with additional absorbent and place into appropriate container for disposal.
Large Spill: Dike large spills using absorbent or impervious material such as clay or sand. Recover and contain as much free liquid as possible for reuse. Allow absorbed material to solidify and scrape up for disposal. Pick up wash liquid with additional absorbent and place in a disposable container. After removal, flush contaminated area thoroughly with water. This material should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: Store the material in a cool, dry, secure area out of reach of children and domestic animals. DO NOT MIX, STORE OR UTILIZE THIS PRODUCT OR SOLUTIONS OF THIS PRODUCT IN GALVANIZED STEEL OR UNLINED STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR TANKS. This product or solutions of this product react with such containers and tanks to produce hydrogen gas which may form a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder’s torch, lighted cigarette or other ignition source. STORE ABOVE 10°F (-12°C) TO KEEP PRODUCT FROM CRYSTALLIZING. Crystals will settle to the bottom. If allowed to crystallize, place in a warm room 68°F (20°C) for several days to redissolve and shake or roll to mix well before using. Do not store food, beverages or tobacco product in the storage area. Prevent eating, drinking tobacco use and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and after handling.
OTHER PRECAUTIONS: Do not contaminate water, food, or feed by storage or disposal.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Refer to product label.
The following recommendations for exposure controls/personal protection are intended for the manufacture, formulation, packaging and use of this product. For commercial applications and/or on-farm applications consult the product label.
INGESTION: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.
SKIN PROTECTION: Long-sleeved shirt, long pants, shoes plus socks. Chemical-resistant gloves, if repeated or prolonged contact.
INHALATION: No special requirement when used as recommended.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this product’s concentrate. Do not reuse them. Follow manufacturer’s instructions for cleaning and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.
WORK HYGIENIC PRACTICES: Wear protective eyewear. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove and wash contaminated clothing before reuse.
EXPOSURE GUIDELINES: Refer to Section 2.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Gardner
ODOR: Mild amine odor
PHYSICAL STATE: Liquid
pH AS SUPPLIED: 4.84
SECTION 10: STABILITY AND REACTIVITY
STABLE UNSTABLE
X
STABILITY: Stable at normal temperature and pressure.
CONDITIONS TO AVOID (STABILITY): Temperatures above 115 deg F (46 deg C) and temperatures below 25 deg C (-5 deg C).
INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizers or bases, mild and galvanized steel, potassium permanganate.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Thermal decomposition can lead to the release of toxic gases including carbon monoxide, nitrogen oxides, phosphorus oxides.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
Oral LD50 (rat) >5,000 mg/Kg
Dermal LD50 (rat) >5,000 mg/Kg
Inhalation LC50 (rat) >1.3 mg/L
Eye Contact: Slightly irritating (Rabbit)
Skin Contact: Not an irritant (Rabbit)
Skin Sensitization: Not a Sensitizer (Guinea Pig)
Reproductive/Developmental Effects: |
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No evidence of mutagenic effects during in vivo or in vitro studies. |
Chronic/subchronic toxicity studies |
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OSHA/NTP/IARC: Not listed. |
Carcinogenicity |
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No data available. |
Other toxicity information |
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None |
Toxicity of other components |
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No data available. |
Target organs |
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Active ingredient (glyphosate isopropylammonium) |
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No data available. |
Inert ingredient |
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Not applicable |
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters or rinsate.
Summary of effects: |
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No data available |
Eco Acute Toxicity: |
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96 Hour LC50, Rainbow Trout: >1000 mg/L |
Eco Chronic Toxicity: |
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No data available. |
Environmental fate: |
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No data available |
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Product disposal – Pesticide wastes may be acutely hazardous. Improper disposal is a violation of federal law. Pesticide, mixtures, or equipment rinse water that cannot be chemically reprocessed must be disposed of according to applicable federal, state or local regulations. Contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional office for guidance.
Container disposal – Dispose of product containers, waste containers, and residues according to label instructions and local, state, and federal health and environmental regulations.
RCRA HAZARD CLASS: Under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste.
SECTION 14: TRANSPORT INFORMATION
Not hazardous under applicable DOT, ICAO/IATA, IMO, TDG and Mexican regulations.
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT): The ingredients of this product are listed on the TSCA inventory or are exempt.
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT):
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
302: Not applicable.
311/312 HAZARD CATEGORIES: Immediate Hazard
313 REPORTABLE INGREDIENTS: Not applicable.
CA PROPOSITION 65: None
SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
| HAZARD RATINGS | NFPA | ||
| HEALTH: | 2 | 0 | MINIMAL |
| FLAMMABILITY: | 1 | 1 | SLIGHT |
| REACTIVITY: | 1 | 2 | MODERATE |
- HIGH
- SEVERE
PREPARATION INFORMATION: MSDS DATE 2-8-10
DISCLAIMER: This product is a registered agricultural chemical and must therefore be used in accordance with the container label directions. The information contained herein is given in good faith and is believed to be correct, but no warrant, express or implied is made. Contact Farmway, Inc. for additional information.